4/3rds is a system developed by Olympus and a few other manufacturers. The size of the sensor is 1/2 the size of a 35 mm film negative. Most dSLRS are close to size of the old APS film negative. This is a 1.5x crop of a 35 mm negative. Cannon of course makes several cameras that are known as full frame; or the same size as a 35 mm negative.
2/3rds is a size of a digital sensor that is used in some consumer digicams. It is much smaller than the 4/3rds sensor. dpReview has a chart somewheres that shows a number of these sensor sizes in comparison.
Confusing this is that the ratio of a 35 mm sensor and an APS size sensor are, I believe, in a ratio of 2/3rds. Which may be what you have heard of as 2/3rds.
Any of the dSLR formats can give you excellent results. I wouldn't worry about which system to use. Instead decide which manufactures system of camera's and lenses you want to use. Be sure to make sure housings are available to take the camera you like underwater. Also remember that the lenses you will want to use UW are probably different than those you would use on land.