Thanks Alex,
As a guide to continue, am I best judging the speed of the subject and adjusting my shutter speed to suit, then finding an aperture to suit the surroundings? or using aperture first if depth of field is the main concern in the photo? No doubt, the more I do this, the more I will know exactly what setting will suit what shot?
I think you will find the best thing to do for Wide Angle work is to set your aperture first based on how far away you are from your subject. This is to get your foreground (strobe lit) subject illuminated correctly. Your strobe will have a chart giving you an approximate distance to fstop setting, something like F16-F22 for 1 foot or less, F11-F16 for 1-2 feet, F8-11 for 2-3 feet, F5.6-8 for 3-4 feet. etc.
1) compose your subject and look to see how far away you are
2) set your fstop based on that distance
3) now set your shutter speed to -1 or so using the light meter in the camera with the camera pointing at the open water column in the direction you are going to shoot, don't cut off the light with the subject in the way.
4) adjust your strobes accordingly
5) fire 
adjust your shutter to bracket the background lighting
adjust your fstop or strobe power to bracket the foreground subject.