Chris, first of all thank you for your attention and help here.
I was using 1/100 for all photographs.
I planned on using manual mode, but on the boat, the housing wheel that makes contact with the camera aperture wheel wasn't making contact. The camera, somehow, was sliding too deep into the housing - thus the housing wheel was behind the camera wheel. I will remedy this by adding a little strip of velcro to prevent the camera from sliding all the way in.
In aperture mode, on my camera, the aperture wheel is another wheel. So I set it to ISO 1000 and 1/100.
Majority of photographs were at f/10. Except the last few where it is obvious I went to a small aperture (f/14 - f/18 - f/20).
I am familiar with cameras and somehow it completely slipped my mind to match minimum shutter speed to lens focal length - i.e: at least a shutter speed of 1/150. Kicking myself for the "cant see the forest for the trees" moment.
This happened because I read a few "introduction to underwater photography" articles and the majority suggested between 1/100 and 1/160. I realize why now - they were using wide angle lenses haha.
I am using the center focal point on my camera. It is the highest performing focus point. And of course I use the back-focus button. I found myself focusing, locking the focus by holding down the BF button, then gently moving myself forward/backwards to get the subject in focus - a human dolly. As you would traditionally with a tripod.
Regarding the focal length 150mm and mis-focusing due to working distance. Very true. Majority of the time I had to press the focus button several times for it to lock on to. While both the camera and lens focused very quickly each time, it still did mis-focus quite a lot. Because I am using a "proprietary" lens - I am unsure which focus ring could/might work.
My rig is very light - I am using three positive-buoyancy floats. I may jettison one for a bit of added negative buoyancy.
My question is, how much air gap should there be between the lens and the flat port lens?
I'm asking because I currently have quite a bit of air/gap.
Does this gap matter or affect anything? Focusing? Light entry into sensor?
I'm asking because at this point I can either procure another port that reduces the empty gap between lens and flat port lens - about $350.
Or procure a used Canon 100 L, the designated port, and focus ring - $1,700.
And if it becomes clear I need a strobe(s), thats further purchasing.
Not trying to skimp or anything. Just trying to see if I can make the Sigma work.
If I can, well and good. If I cannot then it'll be option B.
Next dive, I'll try 1/150 or faster and f/11 or thereabouts and manually control ISO.
Thank you very much.